Queen’s University Belfast joins the group of Climate In Situ users

Queen’s University Belfast joins the group of Climate In Situ users

Dr. Miryam Arredondo-Arechavala (centre) in front of the (packed) Climate system, together with her PhD student Tamsin O’Reilly (left) and her Postdoc Dr. Kristina Holsgrove (right).

At the beginning of October, DENSsolutions installed a Climate G system at the Queen’s University Belfast, Northern Ireland, UK. 

“We are very excited to have the Climate system in-house. It all began about 3 years ago when I started describing these new amazing holders to my colleagues in the Chemistry department. It took some time but couldn’t be happier! We are really looking forward to trying the different experiments that we have been designing for so long… Now it’s time to get to work and hopefully won’t break too many chips on the way!”
Dr. Miryam Arredondo-Arechavala

Applications

The system will be mainly used by Dr. Miryam Arredondo-Arechavala and her group to study ferroelectrics and other functional materials. Alongside this, it will help accelerate research on ionic liquids performed by the QUILL Research Centre (Queen’s University Belfast’s Ionic Liquid Laboratories) and other catalyst projects at Queen’s University Belfast.

The DENSsolutions Climate holder inserted in the Talos TEM for the first time.

The group running the first test experiment using the Climate software.

Installation and first experiment

The system was installed in less than two days by our Climate product manager Ronald Marx. After this, Marx provided hands-on training for the new group of users. The team was able to start their first In Situ Gas & Heating experiment using their own sample of Zeolite particles which was dropcasted on to the Climate Nano-Reactor. Seeing the first results created a lot of enthusiasm among the group of principal investigators and their colleagues from the chemistry department.

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Our partnership with the EPSRC/Jeol Centre for Liquid Phase Electron Microscopy at UCL, London

Our partnership with the EPSRC/Jeol Centre for Liquid Phase Electron Microscopy at UCL, London

DENSsolutions LPEM systems enable advances in Life Science

Dr. Lorena Ruiz-Perez (left) and Prof. Guiseppe Battaglia (right)

On the 12th of November, DENSsolutions in cooperation with UCL and Quantum Design UK will be holding a Stream workshop at the EPRSC/Jeol Centre for Liquid Phase Electron Microscopy (LPEM) facility at UCL, London. At the LPEM facility, opened in 2017, Dr. Lorena Ruiz-Perez uses the DENSsolutions Liquid In Situ solutions to characterise soft organic nanomaterials via TEM imaging. In this article, we take a look at the LPEM research that Ruiz-Perez is doing within the Molecular Bionics lab.

Molecular Bionics

The goal of the group is to mimic specific biological functions and/or introduce operations that do not exist in nature by engineering bionic units made of polymers. This goal is achieved by a multidisciplinary team of chemists, physicists, mathematicians, engineers and biologists.

The LTEM team at the Molecular Bionics group is formed by Prof. Guiseppe Battaglia, director of the facility, Dr. Lorena Ruiz-Perez, manager of the facility. Cesare de Pace and Gabriele Marchello are PhD students involved in the experimental development of LTEM and LTEM image analysis respectively.

Inside the group, Dr. Lorena Ruiz-Perez has been using the DENSsolutions Ocean system to work mainly on two different projects.

Polymer assemblies

For the first project, she has been using the system to investigate soft matter polymer assemblies. As we have shown in one of our earlier articles, these assemblies have the potential to be used for targeted drug delivery inside the human body. These kinds of assemblies have been well studied using Cryogenic electron microscopy (cryo-EM). One of the main advantages of employing LPEM is that it allows us to gain new insights into the dynamic behaviour of these assemblies within a liquid that were not possible using images of the vitrified, i.e. frozen sample. In liquid, you can observe for instance the fluctuation of the polymer assembly membranes and hence investigate significant mechanical properties of the soft materials.

Proteins dynamic behaviour

Their second project involves investigating the dynamic behaviour of proteins in liquid. These proteins move by the so-called ‘Brownian motion’. The group wants to understand the structure of the proteins inside their native environment. While the protein is moving in water, they can capture many different profiles in order to reconstruct a 3D image of the protein structure. There is a minimum frame amount needed for the reconstruction, so the time component becomes fundamental in these in-situ studies. The investigation aims to create a library of proteins, like the RCSB PDB, with information on dynamic processes which can complement the information already supplied by the well established cryo-EM technique. Their first results, studying ferritin proteins, were presented at Manchester 2019*.

Schematic representation showing the temporal evolution of the density map reconstruction process of ferritin. A five second long video was segmented into five one second long sub-videos The brownian particle analysis algorithm extracted about 1000 particle profiles from each sub-video, generating five different density maps. The quality and resolution of the refined density maps resulted in being inversely proportional to the sample exposure time to the electron beam.

Proteins play a pivotal role in our physiological conditions and associated diseases. A deeper understanding of the kinetics governing the mechanistic behaviour of proteins in liquid media can lead to big improvements in drug design and ultimately in general healthcare.

*This manuscript is currently being updated with long molecular dynamics simulations of ferritin in solution.

The new Stream system

Now the group is advancing to the DENSsolutions Stream system, allowing them to do new kinds of experiments. The big advantage of the Stream system is that it can control the bulging of the viewing windows and therefore the liquid thickness. Controlling the bulging is essential for creating reproducible results. In previous LPEM in situ systems, the window bulging could differ between experiments, thus preventing experiment reproducibility.

Now with the Stream system, the bulging can be adjusted precisely for each new experiment, guaranteeing the same level of bulging and, therefore, consistent results. Controlling the liquid thickness is also important to achieve high contrast in organic and biological materials. The liquid thickness can be reduced up to the equilibrium where you have the highest possible resolution combined with a thick enough layer to have a realistic sample environment. 

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Milexia France SAS and DENSsolutions announce new partnership

Milexia France SAS and DENSsolutions announce new partnership

Distribution in France, Luxembourg and Wallonia (Belgium).

DENSsolutions is proud to partner with Milexia France SAS to serve the French, Luxembourg and Wallonian market in Europe. The Milexia France SAS Scientific Instrumentation Division has been a vendor of high-tech scientific instruments since 1981. They offer expert advice, comprehensive solutions, installation and technical testing on-site. DENSsolutions will strengthen their TEM portfolio and together we can build new relationships with French-speaking research groups.

“The DENSsolutions portfolio includes high end and innovative systems for in-situ transmission electron microscopy. These products will perfectly match with the high quality solutions we are used to promote, sell and service on the electron microscopy market for more than 30 years. With DENSsolutions, we are looking to remain active and even to futher develop our presence at the forefront of the new developments in transmission electron microscopy.”

Thierry Grenut, Business Unit Director – Milexia France SAS

“At DENSsolutions we are very excited to have Milexia as our distributor in France and Luxembourg as well as the French-speaking part of Belgium. Milexia is a very respected company in research markets where Electron Microscopy plays an important role. The in situ products and services from DENSsolutions help researchers and engineers develop new technologies that can be used to fight climate change, accelerate energy transition and develop clean and green industrial processes. France is leading many initiatives in all these fields as can be seen in the Paris Agreement on Climate Change. Milexia and DENSsolutions make a fantastic team for helping scientists and engineers advance their research.”

Ben Bormans, CEO -DENSsolutions

 

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Giant Enhancement in the Supercapacitance of NiFe–Graphene Nanocomposites Induced by a Magnetic Field

Giant Enhancement in the Supercapacitance of NiFe–Graphene Nanocomposites Induced by a Magnetic Field

Underlying nanoparticle behaviour revealed by In Situ TEM heating

Original article by Jorge Romero, Helena Prima-Garcia, Maria Varela, Sara G. Miralles, Víctor Oestreicher,
Gonzalo Abellán and Eugenio Coronado.

The development of supercapacitors holds great promise for future energy storage devices with a high cyclability and durability which can be used in our homes, cars and mobile phones to support the transition to sustainable energy. Even though a lot of effort has been devoted to improving the energy and power densities by optimizing the internal configuration of the capacitor, there is still room for further improvement. Now, researchers have found a way to dramatically improve the capacitance of an FeNi3–graphene hybrid capacitor with about 1100% (from 155 to 1850 F g−1), showing high stability with capacitance retention greater than 90% after 10 000 cycles. They achieved this impressive enhancement by cycling the electrode material in the presence of an applied magnetic field of 4000 G.

Fig. 1. Magnetic graphene–FeNi3 nanocomposite particle under applied magnetic field, pristine sample.

Fig. 2. Magnetic graphene–FeNi3 nanocomposite particle under applied magnetic field, after a 30 min annealing at 400 °C and fast quench back to RT. Arrow pointing out the nanometallic clusters.

In Situ TEM heating

To explain the behaviour of the nanoparticles under the external magnetic-field, Prof. Maria Varela from Universidad Complutense de Madrid, Spain and her colleagues performed in situ heating experiments using a DENSsolutions Lightning D9+ heating and biasing double tilt system. The magnetic field of the microscope objective lens combined with the heating stimuli, provided by the DENSsolutions’ system, were able to observe a significant magnetic field and temperature induced metal segregation of Fe/Ni surfaces forming nanometallic clusters of Ni (<5 nm).

Using these results, the authors were able to explain the dramatic increase of the specific capacitance of the device during the cycling. Furthermore, they opened the door to a systematic improvement of the capacitance values of hybrid supercapacitors, moving the research in this area towards the development of magnetically addressable energy-storage devices.

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Visualizing the dynamic behaviours during carbon nanotube growth in extensive detail

Visualizing the dynamic behaviours during carbon nanotube growth in extensive detail

In situ TEM allows for the direct observation of catalytic processes at relevant pressure and temperature conditions

Original article by Xing Huang, Ramzi Farra, Robert Schlögl and Marc-Georg Willinger

Artist impression showing growth of carbon nanotubes via an iron-catalyzed process. © 2019 DENSsolutions All Rights Reserved

Carbon nanotubes (CNTs) hold many promises, for example in energy storage, high-performance catalysis, photovoltaics, and biomedical devices. Although industrial-scale production of CNTs has been realised, the controllability over the diameter, length, and chirality of CNTs is still unsatisfactory. This is largely due to the lack of atomic information on growth dynamics of CNTs and molecular-level understanding of growth mechanisms. Recently, Huang et al. from FHI Berlin and ETH Zürich have performed an In Situ TEM study on CNT growth and disclosed the growth and termination dynamics of CNTs in atomic detail under relevant conditions. 

The stability of the DENSsolutions Nano-Reactor and the possibility to introduce stimuli, like gas and heating, allowed for the live observation at the atomic-scale:

In Situ TEM video made using the DENSsolutions Climate system, showing Fe-catalyzed multiwalled carbon nanotube growth. Temperature: 800 °C, pressure: 178.65 mbar, diluted H2 + C2H4.

Using In Situ TEM gas and heating, the researchers were able to reveal the influence of pressure and temperature on the growth of CNTs. Previous studies were contradictory about the active state of the catalyst. Now with real-time observations of CNT growth at relevant conditions, researchers were able to reveal not only the active phase of the catalyst but also the rich structural dynamics of the catalyst during the course of CNT growth.

In this study, the Nano-Reactor, the core of the DENSsolutions Climate In Situ TEM system, was used as a carrier for the Fe2O3 sample (precursor material for CNT growth), which was then heated in a diluted hydrogen gas flow as a pre-treatment. The In Situ experiment was started at 150 °C and was followed by a step wise increase up to 800 °C in a gas mixture of H2, C2H4 and He.

To accelerate catalyst research, the DENSsolutions Climate system can be delivered with a dedicated Gas Supply system that enables instant switching between gases and precise control over the gas mixture ratio.

Between 450 °C and 650 °C, the reduction of Fe2O3 to Fe3O4 was accompanied by a collapse of larger particles into smaller ones.

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“Thanks to the development of the MEMS-based gas flow Nano-Reactor, we are allowed to perform In Situ experiments inside the chamber of the TEM at relevant conditions. Using the Climate system from DENSsolutions, we have recently carried out a detailed In Situ study on the growth behaviors of CNTs at realistic conditions. On the basis of the real-time observations, we are able to reveal the active structure of the working catalyst and its dynamic re-shaping during the course of CNT growth. Extended observations further reveal three different scenarios for the growth termination of CNTs at the atomic-scale. The presented work provides important insights into understanding the growth and termination mechanisms of CNTs and may serve as an experimental basis for rational design and controlled synthesis of CNTs.”

First and corresponding author – Dr. Xing Huang, ETH Zürich

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In-situ observation of Ge2Sb2Te5 crystallization at the passivated interface

In-situ observation of Ge2Sb2Te5 crystallization at the passivated interface

New insights on crystalization in PCM materials revealed by in situ TEM

Original article by Kun Ren, Yan Cheng, Mengjiao Xia, Shilong Lv, Zhitang Song. Published in Ceramics International, volume 45, issue 15.

In this work the DENSsolutions in situ TEM Lightning system (8 contact, heating and biasing) has been employed by customers from Hangzhou Dianzi University and East China Normal University, China to study the temperature induced nucleation behavior in Ge2Se2Te5 samples In Situ. This material is used as Phase Change Memory (PCM) and the knowledge of the amorphous-to-crystallize transition and the crystallization behavior is essential to its application, especially in nanometer or sub-nanometer modern and future electronics.

Fig. 1. (a) Temperature profile of the thermal pulse applied on the sample, the maximum temperature is 204 °C. (b)–(j) TEM images of the sample at different stages of the heating pulse, with the timestamp shown in the lower right. The scale bar denotes 100 nm. Crystallization directions are marked by red arrows. 

TEM images of the sample at different stages of the heating pulse, with the timestamp shown in the lower right. The scale bar denotes 100 nm. Crystallization directions are marked by red arrows. 

Using fast thermal pulses of 185 °C – 204 °C applied to a FIB lamella, placed on the MEMS-based Nano-chip it was possible to follow the nucleation dynamics in real time and reveal the heterogeneous nature of the nucleation, e.g. crystallization at the interface and the interior of the sample. This distinguished behavior of Ge2Se2Te5 is caused by in-situ deposition of the sample thus avoiding the formation of the covalent bonds between the PCM material and the substrate. Formation of a passivation layer at the PCM-substrate interface can lead to an enhancement of the switching speed in memory with decreasing the cell size.

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Converting CO2 into a valuable energy carrier using a model In2O3 catalyst

Converting CO2 into a valuable energy carrier using a model In2O3 catalyst

New discoveries made possible by In Situ TEM gas and heating

Original article by Athanasia Tsoukalou, Paula M. Abdala, Dragos Stoian, Xing Huang, Marc-Georg Willinger, Alexey Fedorov and Christoph R. Müller. Published in the Journal of the American Chemical Society on 19 July 2019.

Artist impression of methanol synthesis via CO2 hydrogenation using In2O3 catalyst (copyright of the American Chemical Society)

The direct hydrogenation of CO2 to methanol shows promise to be an important technique to reduce the amount of greenhouse gases in the atmosphere and thereby mitigate the negative effects of climate change while producing an important energy carrier. In his contribution to this article, Dr. Xing Huang has used In Situ TEM techniques to assess the limits of In2O3 catalytic performance in CO2 hydrogenation.

In Situ TEM Climate Nano-Reactor study

This catalyst research article by ETH Zürich provides a good demonstration on how in situ TEM experiments can add value to the study of reaction mechanisms. First, the structural changes in the catalyst material were studied with traditional TEM techniques before and after the CO2 reduction. By using the Climate in situ TEM system, the researchers were able to see the dynamics of the reaction, even at much lower pressures (0.8 vs. 20 Bar) than in the original operando experiment.

In Situ TEM video made using the DENSsolutions Climate system, at 300 °C, showing the co-existence of crystalline and amorphous phases as well as the transformation into film structures of the In2O3 catalyst.

Amorphization of the catalyst material inside the Nano-Reactor takes places in a few minutes, compared to hours in the capillary reactor. Re-activation of the catalyst is made easy by the Climate Gas Supply System since the hydrogen plus carbon-dioxide gas flow can be replaced by an oxygen flow at any moment.

“Direct observation using in situ TEM clearly reveals that the structure of In2O3 nanoparticles is highly dynamic under reaction conditions and irradiation of electron beam. The In2O3 is observed to transform into a dynamic structure in which both crystalline and amorphous phases coexist and continuously inter-convert.

This observation is in line with the operando XAS-XRD study revealing formation of the amorphous In0/In2O3 phase with time on stream. To sum up, combination of in situ TEM with other in situ/operando techniques enables to build a direct relationship between the structure and the catalytic performance of the In2O3 catalyst in CO2 hydrogenation to methanol.”

Co-author – Dr. Xing Huang, ETH Zürich

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Interview with Prof. Rafal Dunin-Borkowski, Director of Ernst Ruska-Centre for Microscopy and Spectroscopy with Electrons in Jülich

Interview with Prof. Rafal Dunin-Borkowski, Director of Ernst Ruska-Centre for Microscopy and Spectroscopy with Electrons in Jülich

Fig. 1. Prof. Rafal Dunin-Borkowski. Photo credit: Forschungszentrum Jülich

We interviewed Rafal Dunin-Borkowski, Director of Ernst Ruska-Centre (ER-C) for Microscopy and Spectroscopy with Electrons in Forschungszentrum Jülich. We talked about his road to ER-C, his research into more energy-efficient electronic devices, the growing importance of software and data analysis and the need for automation to improve the measurement of weak signals. 

“I currently have the greatest personal interest in developing techniques for characterizing the functional properties of working electronic and spintronic devices on the smallest scale and in real time in the presence of stimuli such as applied field, voltage, temperature, light, gases and liquids.”

Where does your passion for Electron Microscopy come from?

My passion for electron microscopy was accidental. It came from being taught by Michael Stobbs as an undergraduate and during my Ph.D. He communicated his enthusiasm for developing and applying characterization techniques as a combination of fundamental physics, materials science and other scientific disciplines. Almost every problem involves exploring a new material or phenomenon at close to the atomic scale that no one has studied before.

Can you tell us about your road to the Ernst Ruska-Centre in Jülich?

It was a long road! First of all, I was in Cambridge University, where I completed my undergraduate degree in physics, my Ph.D. and first postdoctoral appointment with Michael Stobbs. I then went to Arizona State University, where I was sponsored by IBM Almaden and worked with David Smith and Molly McCartney on magnetic recording technology. In Arizona, I also worked with John Cowley, Peter Buseck and Michael Scheinfein. I then went to the Department of Materials in Oxford University for 2 years, where I was responsible for using a new field emission microscope with internal and external users. I then obtained a Royal Society University Research Fellowship, returned to Cambridge University and stayed there for almost 7 years, working primarily on off-axis electron holography and related techniques. After Cambridge, I was employed in the Technical University of Denmark to set up a new department, which was called the Center for Electron Nanoscopy. I stayed there for 5 years.

Fig. 2. Prof. Knut Urban. Photo credit: Forschungszentrum Jülich

In 2011, I took over the Institute for Microstructure Research in Forschungszentrum Jülich in Germany when the previous director, Knut Urban, retired. This institute has a long history in electron microscopy technique development and applications, as well as in the operation of the Ernst Ruska-Centre as a user facility. Together with colleagues in Heidelberg and Darmstadt, Knut Urban contributed to the development of spherical aberration correction for transmission electron microscopy in the 1990s. Forschungszentrum Jülich has been operating the Ernst Ruska-Centre as an international user facility since 2004, together with RWTH Aachen University. 50 % of the access time to the instruments is made available to external users, who work with our experienced scientific and technical staff.

As a director, are you still involved in hands-on research?

In the institute that I direct in Jülich, we currently have about 100 active scientists and students, many of whom are paid from 3rd party funding. This means that we respond to external funding decisions, which determine the scientific directions that we work on. It also means that I spend a lot of time raising funding or managing research projects. I therefore have little time to do hands-on research myself. However, I try to stand behind people when they use the electron microscopes and help them with writing software and data analysis. In addition, if any research paper has my name on it I try to make sure that I comment on it line by line. In this way, I try to take as active a role in scientific research as I can.

Which were defining moments that accelerated your career?

Scientifically, there were certain people I worked with who were very helpful in my development
as a scientist. In particular, working with Michael Stobbs, David Smith, John Cowley and others gave
me key experiences and insight. Now, I try to facilitate an environment for people to do the kind of
work that I would like to be doing myself. I look forward to not being a director and going back to
doing hands-on research in the future, because I regard this as my strength.

Fig. 3. Members of the ER-C team (from the left): Dr. Karsten Tillmann, Dr. Juri Barthel, Marita Schmidt and Dr. Andreas Thust.
Photo credit: Forschungszentrum Jülich

What makes the ER-C a unique institute?

The Ernst Ruska-Centre is unique in many ways. It is managed both from the Jülich Research Center and from RWTH Aachen University. This means that there is frequent interaction between people who work in both places, as well as with external users of the facility. We encourage external users to come for as long as possible, so that they are genuine collaborators with our research staff, who each have their own research topic to work on. We also try to encourage our staff to work on technique and instrumentation development to tackle new problems that are brought to us.
The Ernst Ruska-Centre is now moving from research only in the physical sciences to also include soft materials and life science. This change in the breadth of our research allows us to apply techniques, instrumentation and software that have been developed to tackle problems in the physical sciences to soft and biological materials, and vice versa. We are also establishing closer links with other characterization techniques, especially neutron science and synchrotron X-rays, as well as with data scientists.

Fig. 4. Forschungszentrum Jülich – Staff. Photocredit: Forschungszentrum Jülich

What is the role of the ER-C on a global scale?

On a global scale, at first sight the Ernst Ruska-Centre resembles how user facilities work elsewhere, for example in the US National Laboratories. In practice, the working principle is different, in particular with regard to the fact that all of our staff work on as long-term a collaborative basis as possible with incoming scientists and students, in order to optimize experiments and data analysis together with them, rather than concentrating on serving many users.

Do you collaborate with industry to develop new techniques?

In the ER-C, we try to go beyond the techniques and capabilities that are available elsewhere, for example by undertaking ambitious development projects with manufacturers, where we commit our staff time in return for access to technology that is not yet available commercially. Software and instrumentation that is developed in the ER-C is then often licensed back to the manufacturers for the benefit of their future customers and the community as a whole.

In which research topics are you personally interested?

We currently have more than 10 working groups in the ER-C, many of which focus strongly on technique development, as well as on specific materials problems. I have an interest in almost every activity in the institute.

Fig. 5. Artist impression of Spintronics.

However, I currently have the greatest personal interest in developing techniques for characterizing the functional properties of working electronic and spintronic devices on the smallest scale and in real time in the presence of stimuli such as applied field, voltage, temperature, light, gases and liquids. Many of these capabilities have only recently become available. The experiments are carried out at the highest spatial resolution using phase contrast and spectroscopic techniques in both TEM and STEM imaging modes. They also require the development of new approaches for handling the increased amount and rate of data coming from the microscopes.

To what extent do societal challenges determine your choice in your research topics?

Societal priorities have a decisive factor on which scientific topics are funded. In turn, they drive our research. In the Helmholtz Association, we work on the basis of program oriented funding. Every 5 years, our scientific priorities are redefined, in part by societal needs. At the same time, by its very nature much of our research is exploratory and operates over longer timescales, especially with regard to technique and instrumentation development.

Will in situ techniques play a role in the research of ER-C and why are these in situ techniques becoming relevant?

A variety of different problems come under the heading of in situ electron microscopy. Some of our experiments involve “in situ” chemical reactions in gas or liquid environments, while others involve passing electrical currents through or applying magnetic fields to nanoscale materials, or studying the effect of temperature, light or mechanical stress.

One of the scientific priorities of the Hemlholtz Association, which funds much our research, is to understand and develop more energy-efficient devices for future computing applications. In our institute, we use electron microscopy to map the local crystallography, microstructure and functional properties of novel nanoscale devices in real time. We would like to make these measurements on ever faster timescales and are currently developing new hardware and software that we hope will give us access to the sub-nanosecond regime.

What do you expect from DENSsolutions in the future?

We have a partnership agreement and many specimen holders from DENSsolutions, which we are very pleased with. We would like to have an even closer partnership in the future and have many ideas for more ambitious technical developments, as well as for the automation of complicated workflows. In particular, the current practice of performing experiments manually limits our ability to measure very weak signals, which would require repeating the same sequence of steps many thousands of times. For this reason, we need the kind of automation of experiments that is now available in the life sciences. We understand that there is a greater variety of samples and experiments in the physical sciences and that such workflows would then have to be more flexible.

Is your goal with automation to get a higher throughput for your experiments?

This is not the priority. I would primarily like to use automation to improve the measurement of weak signals and to obtaining better statistics in certain measurements, rather than simply to achieve high throughput. We therefore also need more stable specimen stages and a cleaner environment in the microscope column so that the sample does not change over time. There is one other aspect of automation that does not exist at the moment, which is the ability to store samples, for example in inert environments in individual cartridges, until they are no longer needed, perhaps over many years, so that the same region of the same sample can be reassessed quickly, easily and reproducibly as many times as required.

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Real‐Time Imaging of Nanoscale Redox Reactions over Bimetallic Nanoparticles

Real‐Time Imaging of Nanoscale Redox Reactions over Bimetallic Nanoparticles

Shu Fen Tan, See Wee Chee, Zhaslan Baraissov, Hongmei Jin, Teck Leong Tan, Utkur Mirsaidov
Published in Advanced Functional Materials on 16 July 2019

Publication

Video 1: In situ TEM movie of a Pt–Ni rhombic dodecahedron NP undergoing oxidation reaction in 20% O2 / 80% N2 gaseous environment at 400 °C inside a gas cell.
Video 2: In situ TEM movie of a Pt–Ni rhombic dodecahedron NP undergoing reduction reaction in 5% H2 / 95% N2 gaseous environment at 400 °C inside a gas cell.

This recent article from National University of Singapore about the catalyst activity of bimetallic nanoparticles clearly demonstrates the versatility of the Climate G+ gas & heating system that was used for the in situ TEM experiments.

Figure S4. In situ TEM images showing the evolution of Pt–Ni NPs (A) before and (B) after the oxidation (20% O2 / 80% N2) reaction followed by (C) the reduction (5% H2 / 95% N2) reaction at 400 °C inside a gas cell. Here, t = 0 s marks the start of 20% O2 / 80% N2 flow. At t = 133.1 s, the gas mixture was switched to 5% H2 / 95% N2.

Fast switching between oxidizing and reducing gas conditions allows direct observation of the morphological changes in the catalyst material. The video’s above also demonstrate the UHR image stability at in situ conditions.

Combining the images and video’s from this experiment with SAED, EDS and Mass Spectroscopy results gives valuable information about the areas where the catalyst is most active.

Nanoscience Instruments and DENSsolutions announce new partnership

Nanoscience Instruments and DENSsolutions announce new partnership

DENSsolutions is proud to partner with Nanoscience Instruments to serve the US and Canadian markets. Nanoscience Instruments combines expertise in microscopy and surface science instrumentation with real-world solutions. This partnership will provide a synergistic fit to the core competencies of Nanoscience Instruments and the markets they serve.

Sebastian Kossek, co-owner of Nanoscience Instruments

“The DENSsolutions In Situ TEM solutions allow researchers to fully investigate real-world phenomena and achieve breakthrough science. The expansion to our range of products will further expand our reach into key strategic markets,” says Sebastian Kossek, co-owner of Nanoscience Instruments.

“As a company that specializes in surface science characterization and measurement instrumentation solutions, we are excited to have additional tools that are synergistic to our current and future customer base.”

“As scientists and researchers are looking to solve macro modern-day global challenges which society is facing, they need to understand materials down to the atomic level. The innovative and powerful In Situ TEM solutions DENSsolutions provides helps these researchers change the world, one atom at a time,” says Ben Bormans, CEO DENSsolutions.

“By incorporating all stages of the development model, In Situ TEM unlocks unprecedented research capabilities and moves nanoscience to the next level.”

Ben Bormans, CEO of DENSsolutions

Ben Bormans, CEO of DENSsolutions

“As scientists and researchers are looking to solve macro modern-day global challenges which society is facing, they need to understand materials down to the atomic level. The innovative and powerful In Situ TEM solutions DENSsolutions provides helps these researchers change the world, one atom at a time,” says Ben Bormans, CEO DENSsolutions.

“By incorporating all stages of the development model, In Situ TEM unlocks unprecedented research capabilities and moves nanoscience to the next level.”

Mark Flowers, co-owner of Nanoscience Instruments.

“The partnership with DENSsolutions opens new avenues for the current customer base and find additional overlaps with the other technologies we currently provide,” says Mark Flowers, co-owner of Nanoscience Instruments.

“Observing processes ‘on-site’ as they are occurring and under changing external stimuli is the paramount goal of In Situ, time resolved techniques.”

For more information about Nanoscience Instruments and the products and services they provide, visit us online at www.nanoscience.com